Two-dimensional MOF-based liquid marbles: surface energy calculations and efficient oil–water separation using a ZIF-9-III@PVDF membrane

Author:

Saini Haneesh1ORCID,Kallem Parashuram23ORCID,Otyepková Eva4ORCID,Geyer Florian5ORCID,Schneemann Andreas6ORCID,Ranc Vaclav78ORCID,Banat Fawzi23ORCID,Zbořil Radek79ORCID,Otyepka Michal710ORCID,Fischer Roland A.11ORCID,Jayaramulu Kolleboyina1ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Jammu, Jammu & Kashmir, 181221, India

2. Center for Membranes and Advanced Water Technology (CMAT), Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates

3. Department of Chemical Engineering, Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates

4. Department of Physical Chemistry, Faculty of Science, Palacký University Olomouc, 17. Listopadu 12, 783 46 Olomouc, Czech Republic

5. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

6. Lehrstuhl für Anorganische Chemie I, Technische Universität Dresden, Bergstr. 66, 01069 Dresden, Germany

7. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute (CATRIN), Palacký University Olomouc, Šlechtitelů 27, 783 71, Olomouc, Czech Republic

8. Institute of Molecular and Translational Medicine, Faculty of Medicine and Dentistry, Palacky University, Olomouc, Czech Republic

9. Nanotechnology Centre, Centre of Energy and Environmental Technologies, VŠB–Technical University of Ostrava, 17, listopadu 2172/15, 708 00 Ostrava-Poruba, Czech Republic

10. IT4Innovations, VSB – Technical University of Ostrava, 17. Listopadu 2172/15, Poruba, 708 00 Ostrava, Czech Republic

11. Department of Chemistry and Catalysis Research Centre, Chair of Inorganic and Metal-Organic Chemistry, Technical University of Munich, 85748 Garching, Germany

Abstract

Facile, economically viable route towards 2D superhydrophobic–oleophilic ZIF-9-III readily forming liquid marbles in contact with water droplets is presented. ZIF-9-III@PVDF membranes can be used for efficient oil–water separation.

Funder

Science and Engineering Research Board

Ministerstvo Školství, Mládeže a Tělovýchovy

Deutsche Forschungsgemeinschaft

Khalifa University of Science, Technology and Research

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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