Operando scanning electrochemical microscopic investigation and visualization of NRR-HER competition in electrochemical NH3 synthesis

Author:

Gupta Divyani1ORCID,Kafle Alankar1,Singh Man1,Dahare Devyani1,Nagaiah Tharamani C.1ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001, India

Abstract

Operando-SECM investigations are utilised for the first time to study the NRR-HER competition during NH3 synthesis over Cu-Ni4B3 catalyst with high notable NRR activity (F.E.: 43.42%; yield rate: 684 μgNH3 h−1 mgcat.−1 at −0.3 V in 0.1 M H2SO4).

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Indian Institute of Technology Ropar

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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