Properties of gaseous closo-[B6X6]2− dianions (X = Cl, Br, I)-Reference-Cited by-同舟云学术

Properties of gaseous closo-[B6X6]2− dianions (X = Cl, Br, I)

Published:2020 Issue:31 Volume:22 Page:17713-17724
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rohdenburg Markus¹²³⁴^ORCID,Yang Zheng⁵⁶⁷⁸^ORCID,Su Pei⁹¹⁰¹¹⁸^ORCID,Bernhardt Eduard¹²¹³¹⁴¹⁵⁴,Yuan Qinqin⁵⁶⁷⁸^ORCID,Apra Edoardo¹⁶⁶⁷⁸^ORCID,Grabowsky Simon¹⁷¹⁸¹⁹²⁰^ORCID,Laskin Julia⁹¹⁰¹¹⁸^ORCID,Jenne Carsten¹²¹³¹⁴¹⁵⁴^ORCID,Wang Xue-Bin⁵⁶⁷⁸^ORCID,Warneke Jonas²¹²²²³⁴²⁴^ORCID

Affiliation:

1. Institut für Angewandte und Physikalische Chemie

2. Universität Bremen

3. 28359 Bremen

4. Germany

5. Physical Sciences Division

6. Pacific Northwest National Laboratory

7. Richland

8. USA

9. Department of Chemistry

10. Purdue University

11. West Lafayette

12. Anorganische Chemie

13. Fakultät für Mathematik und Naturwissenschaften

14. Bergische Universität Wuppertal

15. 42119 Wuppertal

16. Environmental Molecular Sciences Laboratory

17. Departement für Chemie und Biochemie

18. Universität Bern

19. 3012 Bern

20. Switzerland

21. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie

22. Universität Leipzig

23. 04103 Leipzig

24. Leibniz Institute of Surface Engineering (IOM)

Abstract

The electronic properties, fragmentation by collision-induced dissociation and bond properties of gaseous closo-[B₆X₆]²⁻ (X = Cl, Br, I) dianions are discussed and compared to their larger-sized [B₁₂X₁₂]²⁻ analogues.

Funder

U.S. Department of Energy

Volkswagen Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02581J

Reference71 articles.

1. Synthesis, Crystal Structure, and Reactivity of the Strong Methylating Agent Me2B12Cl12

2. Synthesis, Characterization, and Crystal Structures of Silylium Compounds of the Weakly Coordinating Dianion [B12Cl12]2−