Charge transport in hybrid platinum/molecule/graphene single molecule junctions

Author:

He Chunhui12341,Zhang Qian12341,Gao Tingwei12341,Liu Chenguang5234,Chen Zhenyu1678,Zhao Cezhou5234,Zhao Chun5234,Nichols Richard J.1678ORCID,Dappe Yannick J.910111213,Yang Li12341ORCID

Affiliation:

1. Department of Chemistry

2. Xi’an-Jiaotong Liverpool University

3. Suzhou

4. China

5. Department of Electrical and Electronic Engineering

6. University of Liverpool

7. Liverpool

8. UK

9. SPEC

10. CEA

11. CNRS

12. Université Paris-Saclay

13. CEA Saclay

Abstract

The single molecule conductance of hybrid platinum/alkanedithiol/graphene junctions has been investigated with a focus on understanding the influence of employing two very different contact types, namely the relatively weak van der Waals coupling at the graphene interface and the strong bond dipole at the Pt–S interface.

Funder

National Natural Science Foundation of China

State Key Laboratory of Materials Processing and Die and Mould Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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