Solvent determines the formation and properties of metal–organic frameworks
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Sciences
2. Key Laboratory of Colloid and Interface and Thermodynamics
3. Institute of Chemistry
4. Chinese Academy of Sciences
5. China
Abstract
Herein we synthesized Cu3(BTC)2 nanocrystals in a series of water/ethanol solvent systems at room temperature. The size and porosity of Cu3(BTC)2 can be easily modulated by controlling the composition of the mixed solvent.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA02440D
Reference45 articles.
1. Sorption of H2 to Open Metal Sites in a Metal–Organic Framework: A Symmetry-Adapted Perturbation Theory Analysis
2. Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake
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4. Metal–organic framework nanosheets in polymer composite materials for gas separation
5. Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery
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