Unraveling the origin of improved photovoltaic performance in acceptor–acceptor-structured perylene-diimide-based polymeric acceptors through partially fluorinating benzo[c][1,2,5]thiadiazole

Author:

Tong Junfeng1ORCID,Liu Wuyan1,Huang Yubo1,Li Zheyu1,Wang Yan2,Bai Suiyan1,Liang Zezhou3,Yan Lihe3ORCID,Li Jianfeng1ORCID,Xia Yangjun1ORCID

Affiliation:

1. Gansu Provincial Engineering Research Center for Organic Semiconductor Materials and Application Technology, School of Materials Science and Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, China

2. Engineering Research Center of Advanced Ferroelectric Functional Materials, College of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Key Laboratory of Phytochemistry of Shaanxi Province, Baoji, 721013, P. R. China

3. Key Laboratory for Physical Electronics and Devices of the Ministry of Education & Shaanxi Key Lab of Information Photonic Technique, School of Electronics and Information Engineering, Xi’an Jiaotong University, Xi’an, 710049, China

Abstract

PPDI-DTFBT not only possessed better molecular planarity and lower exciton binding energy (Eb) but also exhibited faster and efficient exciton dissociation and transfer, leading to an increased PCE of 6.04%.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Gansu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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