Air-stable four-coordinate cobalt(<scp>ii</scp>) single-ion magnets: experimental and <i>ab initio</i> ligand field analyses of correlations between dihedral angles and magnetic anisotropy-Reference-Cited by-同舟云学术

Air-stable four-coordinate cobalt(ii) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy

Published:2023 Issue:23 Volume:14 Page:6355-6374
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gupta Sandeep K.¹^ORCID,Rao Shashank V.²^ORCID,Demeshko Serhiy¹,Dechert Sebastian¹^ORCID,Bill Eckhard³,Atanasov Mihail²⁴^ORCID,Neese Frank²^ORCID,Meyer Franc¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany

2. Max Planck Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

3. Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470 Mülheim an der Ruhr, Germany

4. Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Akad. Georgi Bontchev Street 11, 1113 Sofia, Bulgaria

Abstract

Magneto-structural correlations for air-stable four-coordinate Co(ii) complexes reveal the dependence of magnetic properties on the dihedral twist angle and establish valuable design guidelines for achieving high magnetic anisotropy.

Funder

Max-Planck-Gesellschaft

Alexander von Humboldt-Stiftung

Georg-August-Universität Göttingen

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00813D

Reference112 articles.