Key structural features to favour imines over hydrates in water: pyridoxal phosphate as a muse-Reference-Cited by-同舟云学术

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Key structural features to favour imines over hydrates in water: pyridoxal phosphate as a muse

Published:2024 Issue:27 Volume:15 Page:10408-10415
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Esteve Ferran¹^ORCID,Rieu Tanguy¹^ORCID,Lehn Jean-Marie¹^ORCID

Affiliation:

1. Laboratoire de Chimie Supramoléculaire, Institut de Science et d’Ingénierie Supramoléculaires (ISIS), Université de Strasbourg, 8 allée Gaspard Monge, Strasbourg, 67000, France

Abstract

The key structural features that aldehydes should present to favour imines over hydrates in water are investigated at different pD values. Sulfonate ortho-substituents remarkably stabilize iminium derivatives while disfavouring hydrate formation.

Funder

H2020 European Research Council

Fundación Ramón Areces

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02206H

Reference48 articles.

1. Dynamic imine chemistry

2. Covalent Organic Frameworks: Design, Synthesis, and Functions

3. Perspectives in Chemistry-Aspects of Adaptive Chemistry and Materials

4. Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation

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