Aromatic heterobicycle-fused porphyrins: impact on aromaticity and excited state electron transfer leading to long-lived charge separation-Reference-Cited by-同舟云学术

Aromatic heterobicycle-fused porphyrins: impact on aromaticity and excited state electron transfer leading to long-lived charge separation

Published:2022 Issue:34 Volume:13 Page:9880-9890
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Moss Austen¹,Jang Youngwoo¹,Arvidson Jacob¹,Nesterov Vladimir N.¹,D'Souza Francis¹^ORCID,Wang Hong¹^ORCID

Affiliation:

1. Department of Chemistry, University of North Texas, 1155 Union Circle, #305070, Denton, TX 76203-5017, USA

Abstract

π-Extended porphyrins fused with benzo[4,5]imidazo[2,1-a]isoindole, showing unique electronic and photophysical properties, were newly synthesized. A long-lived charge-separated state was revealed upon coordination of C60 to zinc porphyrin AMIm-2.

Funder

U.S. Department of Energy

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03238D

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