Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles-Reference-Cited by-同舟云学术

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Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles

Published:2017 Issue:11 Volume:15 Page:2376-2384
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Drouin Myriam¹²³⁴⁵,Tremblay Sébastien¹²³⁴⁵,Paquin Jean-François¹²³⁴⁵^ORCID

Affiliation:

1. CCVC

2. PROTEO

3. Département de chimie

4. 1045 avenue de la Médecine

5. Université Laval

Abstract

The catalytic synthesis of monofluoroalkenes bearing a malonate or its derivatives at the β position from various 3,3-difluoropropenes is presented.

Funder

Université Laval

Natural Sciences and Engineering Research Council of Canada

Fonds de Recherche du Québec - Nature et Technologies

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00376E

Reference49 articles.

1. T. Hiyama , in Organofluorine Compounds; Chemistry and Applications, ed. H. Yamamoto, Springer, New York, 2000 and references cited therein

2. Understanding organofluorine chemistry. An introduction to the C–F bond

3. Fluorine in Pharmaceuticals: Looking Beyond Intuition

4. Fluorine in medicinal chemistry

5. The Many Roles for Fluorine in Medicinal Chemistry

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