2-Mercaptoimidazolium halides: structural diversity, stability and spontaneous racemisation

Author:

Braun Doris E.1234ORCID,Lampl Martin56234,Kahlenberg Volker7234ORCID,Wurst Klaus56234,Schottenberger Herwig56234ORCID,Hummel Michael89101112ORCID,Griesser Ulrich J.1234ORCID

Affiliation:

1. Institute of Pharmacy

2. University of Innsbruck

3. 6020 Innsbruck

4. Austria

5. Institute of General

6. Inorganic and Theoretical Chemistry

7. Institute of Mineralogy and Petrography

8. School of Chemical Engineering

9. Department of Bioproducts and Biosystems

10. Aalto University

11. 00076 Aalto

12. Finland

Abstract

The complementarity of experiment and theory unravelled structural features, potential polymorphism, moisture and temperature dependent stability and the racemisation behaviour of 2-mercaptoimidazolium salts.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference71 articles.

1. J. Jacques , A.Collet and S. H.Wilen , Enantiomers, Racemates and Resolutions , Krieger Publishing Company , Malabar, Florida , 1994

2. Polymorphism of racemic felodipine and the unusual series of solid solutions in the binary system of its enantiomers

3. Structure and Stability of Racemic and Enantiopure Pimobendan Monohydrates: On the Phenomenon of Unusually High Stability

4. Phase changes and chemical reactions in molecular crystals

5. J. Bernstein , Polymorphism in Molecular Crystals , Clarendon Press , Oxford , 2002

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