Mechanistic insights into hydroacylation with non-chelating aldehydes-Reference-Cited by-同舟云学术

Mechanistic insights into hydroacylation with non-chelating aldehydes

Published:2015 Issue:1 Volume:6 Page:174-180
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Murphy Stephen K.¹²³⁴¹,Bruch Achim¹²³⁴,Dong Vy M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of California

3. Irvine

4. USA

Abstract

Rhodium catalysts with small-bite-angle diphosphines enable branched-selective hydroacylation of 2-vinylphenols via C–H activation of non-chelating aldehydes.

Funder

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC02026J

Reference65 articles.

1. Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

2. Double-Chelation-Assisted Rh-Catalyzed Intermolecular Hydroacylation

3. Double-Chelation-Assisted Rh-Catalyzed Intermolecular Hydroacylation between Salicylaldehydes and 1,4-Penta- or 1,5-Hexadienes

4. Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides

5. β-hydroxy ketones prepared by regioselective hydroacylation

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