Tuning the mechanical properties of molecular perovskites by controlling framework distortions via A-site substitution

Author:

Kronawitter Silva M.1ORCID,Park Shinjoo1,Hallweger Sebastian A.1ORCID,Myatt Emily2ORCID,Pitcairn Jem2,Cliffe Matthew J.2ORCID,Daisenberger Dominik3ORCID,Drees Markus1,Kieslich Gregor1ORCID

Affiliation:

1. Department of Chemistry, TUM School of Natural Sciences, Technical University of Munich, Lichtenbergstraße 4, 85748 Garching, Germany

2. School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK

3. Diamond Light Source Ltd., Diamond House, Harwell Campus, Didcot OX11 ODE, UK

Abstract

In this work, we quantify the link between framework distortions and mechanical properties in molecular perovskites, showing that increasing framework distortions translates to a reduced compressibility.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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