The addition of bromine and iodine to palladacyclopentadienyl complexes bearing bidentate heteroditopic P−N spectator ligands derived from differently substituted quinolinic frames. The unexpected evolution of the reaction-Reference-Cited by-同舟云学术

The addition of bromine and iodine to palladacyclopentadienyl complexes bearing bidentate heteroditopic P−N spectator ligands derived from differently substituted quinolinic frames. The unexpected evolution of the reaction

Published:2015 Issue:33 Volume:44 Page:15049-15058
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Canovese Luciano¹²³⁴,Visentin Fabiano¹²³⁴,Scattolin Thomas¹²³⁴,Santo Claudio¹²³⁴,Bertolasi Valerio⁵⁶⁷⁴

Affiliation:

1. Dipartimento di Scienze Molecolari e Nanosistemi

2. Università Ca’ Foscari

3. Venice

4. Italy

5. Dipartimento di Chimica e Centro di Strutturistica Diffrattometrica

6. Università di Ferrara

7. Ferrara

Abstract

The palladacyclopentadienyl complexes with substituted phosphoquinolines react with halogens giving σ-butadienyl or a zwitterionic derivative depending on the ligand structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01884F

Reference68 articles.

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4. The Heck Reaction as a Sharpening Stone of Palladium Catalysis

5. Anionic Pd(0) and Pd(II) Intermediates in Palladium-Catalyzed Heck and Cross-Coupling Reactions

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