Bridging photochemistry and photomechanics with NMR crystallography: the molecular basis for the macroscopic expansion of an anthracene ester nanorod

Author:

Chalek Kevin R.1234,Dong Xinning1234,Tong Fei1234,Kudla Ryan A.1234,Zhu Lingyan1234,Gill Adam D.5234,Xu Wenwen6784,Yang Chen1234,Hartman Joshua D.1234ORCID,Magalhães Alviclér910111213ORCID,Al-Kaysi Rabih O.1415161718ORCID,Hayward Ryan C.6784ORCID,Hooley Richard J.1234ORCID,Beran Gregory J. O.1234ORCID,Bardeen Christopher J.1234ORCID,Mueller Leonard J.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of California-Riverside

3. Riverside

4. USA

5. Department of Biochemistry

6. Department of Chemical and Biological Engineering

7. University of Colorado Boulder

8. Boulder

9. Department of Organic Chemistry

10. Institute of Chemistry

11. Federal University of Rio de Janeiro

12. Rio de Janeiro

13. Brazil

14. College of Science and Health Professions-3124

15. King Saud Bin Abdulaziz University for Health Sciences

16. King Abdullah International Medical Research Center

17. Ministry of National Guard Health Affairs

18. Riyadh 11426

Abstract

NMR crystallography establishes absolute unit-cell orientations relative to the shape change, revealing the atomic-resolution mechanism for the nanorod's photomechanical response.

Funder

Office of Naval Research

National Institute of General Medical Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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