Pandora's box of binary tungsten iodides

Author:

Ströbele Markus12345ORCID,Meyer Hans-Jürgen12345ORCID

Affiliation:

1. Abteilung für Festkörperchemie und Theoretische Anorganische Chemie

2. Institut für Anorganische Chemie

3. Universität Tübingen

4. D-72076 Tübingen

5. Germany

Abstract

More than 20 binary tungsten iodides have been discovered. This was possible due to a new synthesis of W3I12 through halide exchange reaction and by thermal scanning. Depending on the I2 partial pressure compounds can incorporate or release I2. On heating they undergo self-reduction. Some tungsten iodide clusters can be directly transferred into solution.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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