Pandora's box of binary tungsten iodides
Author:
Affiliation:
1. Abteilung für Festkörperchemie und Theoretische Anorganische Chemie
2. Institut für Anorganische Chemie
3. Universität Tübingen
4. D-72076 Tübingen
5. Germany
Abstract
More than 20 binary tungsten iodides have been discovered. This was possible due to a new synthesis of W3I12 through halide exchange reaction and by thermal scanning. Depending on the I2 partial pressure compounds can incorporate or release I2. On heating they undergo self-reduction. Some tungsten iodide clusters can be directly transferred into solution.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04004D
Reference46 articles.
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