Near-infrared emitting copper(<scp>i</scp>) complexes with a pyrazolylpyrimidine ligand: exploring relaxation pathways-Reference-Cited by-同舟云学术

Near-infrared emitting copper(i) complexes with a pyrazolylpyrimidine ligand: exploring relaxation pathways

Published:2022 Issue:7 Volume:51 Page:2898-2911
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shekhovtsov Nikita A.¹^ORCID,Kokina Tatyana E.¹,Vinogradova Katerina A.¹^ORCID,Panarin Andrey Y.²,Rakhmanova Marianna I.¹,Naumov Dmitry Y.¹,Pervukhina Natalya V.¹,Nikolaenkova Elena B.³,Krivopalov Viktor P.³,Czerwieniec Rafał⁴,Bushuev Mark B.¹^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia

2. B. I. Stepanov Institute of Physics NASB, Nezalezhnasti Ave., 68, 220072, Minsk, Belarus

3. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia

4. Institut für Physikalische und Theoretische Chemie, Universität Regensburg, Universitätsstrasse 31, Regensburg, D-93053, Germany

Abstract

Mononuclear copper(i) complexes demonstrate T1 → S0 phosphorescence in the near-infrared region associated with ligand-to-metal charge transfer. The most effective intersystem crossing channels are S6 → T7, S6 → T8 and S10 → T12.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04325K

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