Iron(<scp>iv</scp>) complexes with tetraazaadamantane-based ligands: synthesis, structure, applications in dioxygen activation and labeling of biomolecules-Reference-Cited by-同舟云学术

Iron(iv) complexes with tetraazaadamantane-based ligands: synthesis, structure, applications in dioxygen activation and labeling of biomolecules

Published:2022 Issue:11 Volume:51 Page:4284-4296
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Golovanov Ivan S.¹^ORCID,Leonov Anton V.¹²,Lesnikov Vladislav K.¹^ORCID,Pospelov Evgeny V.¹²,Frolov Kirill V.³^ORCID,Korlyukov Alexander A.⁴^ORCID,Nelyubina Yulia V.⁴,Novikov Valentin V.⁴,Sukhorukov Alexey Yu.¹⁵⁶^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prospect, 47, Moscow, 119991, Russia

2. M. V. Lomonosov Moscow State University, Leninskiye Gory, 1, Moscow, 119991, Russia

3. Shubnikov Institute of Crystallography of FSRC “Crystallography and Photonics”, Russian Academy of Sciences, Leninsky prospect, 59, Moscow, 119333, Russia

4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, Moscow, 119991, Russia

5. Plekhanov Russian University of Economics, Stremyanny per. 36, Moscow, 117997, Russia

6. D. Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, Moscow, 125047, Russia

Abstract

This paper describes a unique example of a stable non-heme iron(iv) complex formed by oxidation with air. The complex enables dioxygen activation by serving as a mimetic of thiol oxidase.

Funder

Russian Foundation for Basic Research

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04104E

Reference70 articles.

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4. Two interconverting Fe(IV) intermediates in aliphatic chlorination by the halogenase CytC3

5. A Mononuclear Non-heme Iron(III)–Peroxo Complex with an Unprecedented High O–O Stretch and Electrophilic Reactivity

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