FLP-type nitrile activation and cyclic ether ring-opening by halo-borane nonagermanide-cluster Lewis acid–base pairs-Reference-Cited by-同舟云学术

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FLP-type nitrile activation and cyclic ether ring-opening by halo-borane nonagermanide-cluster Lewis acid–base pairs

Published:2021 Issue:20 Volume:12 Page:6969-6976
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wallach Christoph¹²³⁴,Geitner Felix S.¹²³⁴,Fässler Thomas F.¹²³⁴^ORCID

Affiliation:

1. Department Chemie

2. Technische Universität München

3. 85747 Garching b. München

4. Germany

Abstract

The reactivity of the lone pairs in polyhedral Zintl anions is shown by the reaction of the bis-silylated cluster [Ge₉{Si(TMS)₃}₂]²⁻ accomplishing cyclic-ether ring-opening or nitrile activation according to a FLP-like mechanism with bromo-boranes.

Funder

Bayerisches Staatsministerium für Wirtschaft, Infrastruktur, Verkehr und Technologie

Studienstiftung des Deutschen Volkes

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00811K

Reference65 articles.

1. Main-group elements as transition metals

2. The broadening reach of frustrated Lewis pair chemistry

3. Frustrated Lewis Pairs: From Concept to Catalysis

4. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

5. Frustrated Lewis Pairs and Ring-Opening of THF, Dioxane, and Thioxane

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2. A Series of Cyclopentadienyl Lanthanum Complexes with Metalloid Germanium Clusters;Inorganic Chemistry;2024-07-10

3. Zintl Clusters as a Platform for Lewis Acid Catalysis;Inorganic Chemistry;2024-05-30

4. Alkane Elimination Preparation of Heterobimetallic MoAl Tetranuclear and Binuclear Complexes Promoting THF Ring Opening;Inorganics;2024-02-28

5. Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines;Organometallics;2024-01-26

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