CO<sub>2</sub> and palladium enabled highly chemoselective hydroxylation of <i>gem</i>-difluorocyclopropanes-Reference-Cited by-同舟云学术

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CO₂ and palladium enabled highly chemoselective hydroxylation of gem-difluorocyclopropanes

Published:2024 Issue:9 Volume:11 Page:2494-2501
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Xingben¹,Xiao Fang¹,Patureau Frederic W.¹^ORCID

Affiliation:

1. Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

Abstract

A mild chemoselective CO2 and palladium mediated hydroxylation method of gem-difluorocyclopropanes is herein reported, in the presence of water. A broad functional group tolerance and multiple mechanistic experiments are described and discussed.

Funder

China Scholarship Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00106K

Reference78 articles.

1. Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment

2. Human capital and CO2 emissions in the long run

3. Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide

4. Opportunities and Challenges for Catalysis in Carbon Dioxide Utilization

5. Radical Carboxylative Cyclizations and Carboxylations with CO2

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