1-Azahomocubane-Reference-Cited by-同舟云学术

1-Azahomocubane

Published:2023 Issue:11 Volume:14 Page:2821-2825
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fahrenhorst-Jones Tyler¹^ORCID,Marshall David L.²^ORCID,Burns Jed. M.¹^ORCID,Pierens Gregory K.³^ORCID,Hormann Robert E.⁴,Fisher Allison M.⁴,Bernhardt Paul V.¹^ORCID,Blanksby Stephen J.²^ORCID,Savage G. Paul⁵,Eaton Philip E.⁴,Williams Craig M.¹^ORCID

Affiliation:

1. School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, 4072, Queensland, Australia

2. Central Analytical Research Facility and School of Chemistry and Physics, Queensland University of Technology, Brisbane, 4000, Queensland, Australia

3. Centre for Advanced Imaging, University of Queensland, Brisbane, 4072, Queensland, Australia

4. Department of Chemistry, University of Chicago, Chicago, Illinois 60637, USA

5. CSIRO Manufacturing, Ian Wark Laboratory, Melbourne, 3168, Victoria, Australia

Abstract

1-Azahomocubane has been prepared 56 years after the parent hydrocarbon. Introduction of a nitrogen atom into this constrained polycyclic environment resulted in minimal changes to the framework geometry, with s-character of the nitrogen lone pair increasing due to strain.

Funder

Australian Research Council

University of Queensland

Commonwealth Scientific and Industrial Research Organisation

University of Chicago

Queensland University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00001J