Formation of a water-mediated assembly of two neutral copper(ii) Schiff base fragments with a Cu2(NCS)4moiety: exploration of non-covalent C–H⋯π(bimetallo ring) interactions-Reference-Cited by-同舟云学术

Formation of a water-mediated assembly of two neutral copper(ii) Schiff base fragments with a Cu2(NCS)4moiety: exploration of non-covalent C–H⋯π(bimetallo ring) interactions

Published:2018 Issue:12 Volume:20 Page:1679-1689
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Roy Sourav¹²³⁴⁵,Drew Michael G. B.⁶⁷⁸⁹,Bauzá Antonio¹⁰¹¹¹²¹³^ORCID,Frontera Antonio¹⁰¹¹¹²¹³^ORCID,Chattopadhyay Shouvik¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Inorganic Section

3. Jadavpur University

4. Kolkata – 700032

5. India

6. School of Chemistry

7. The University of Reading

8. Reading RG6 6AD

9. UK

10. Departamento de Química

11. Universitat de les Illes Balears

12. 07122 Palma

13. Spain

Abstract

The energetic features of dimer formation and water encapsulation in an interesting copper(ii) Schiff base complex, [(CuL)₂⊂(H₂O)][Cu₂(μ_1,3-NCS)₂(NCS)₂], have been studied using DFT calculations.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CE/C7CE01473B

Reference94 articles.

1. Two new hetero-dinuclear nickel(II)/zinc(II) complexes with compartmental Schiff bases: Synthesis, characterization and self assembly

2. Advancement in stereochemical aspects of Schiff base metal complexes

3. Magnetic assemblies based on Mn(III) salen analogues