Enantio- & chemo-selective preparation of enantiomerically enriched aliphatic nitro alcohols using Candida parapsilosis ATCC 7330-Reference-Cited by-同舟云学术

Enantio- & chemo-selective preparation of enantiomerically enriched aliphatic nitro alcohols using Candida parapsilosis ATCC 7330

Published:2015 Issue:90 Volume:5 Page:73807-73813
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Venkataraman Sowmyalakshmi¹²³⁴⁵,Chadha Anju¹²³⁴⁵

Affiliation:

1. Laboratory of Bioorganic Chemistry

2. Department of Biotechnology

3. Indian Institute of Technology Madras

4. Chennai 600 036

5. India

Abstract

Enantiomerically pure β- and γ-nitro alcohols were prepared from their respective nitro ketones by asymmetric reduction using Candida parapsilosis ATCC 7330 under optimized reaction conditions (ee up to >99%; yields up to 76%).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA13593A

Reference67 articles.

1. Asymmetric reduction of β- and γ-nitro ketones by bakers' yeast

2. Cu(II)-Macrocylic [H4]Salen Catalyzed Asymmetric Nitroaldol Reaction and Its Application in the Synthesis of α1-Adrenergic Receptor Agonist (R)-Phenylephrine

3. Asymmetric syntheses of pheromones for Bactrocera nigrotibialis, Andrena wilkella, and Andrena haemorrhoa F from a chiral nitro alcohol

4. Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)–Cu(OAc)2·H2O complex

5. Charge-Transfer Interactions: An Efficient Tool for Recycling Bis(oxazoline)-Copper Complexes in Asymmetric Henry Reactions

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