Synthesis, crystal structure and hydrolysis of novel isomeric cage (P–C/P–O)-phosphoranes on the basis of 4,4,5,5-tetramethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane and hexafluoroacetone-Reference-Cited by-同舟云学术

Synthesis, crystal structure and hydrolysis of novel isomeric cage (P–C/P–O)-phosphoranes on the basis of 4,4,5,5-tetramethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane and hexafluoroacetone

Published:2016 Issue:89 Volume:6 Page:85745-85755
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Khasiyatullina Nadezhda R.¹²³⁴,Mironov Vladimir F.¹²³⁴⁵,Krivolapov Dmitry B.¹²³⁴,Mironova Ekaterina V.¹²³⁴⁵,Gnezdilov Oleg I.⁶²⁷⁴

Affiliation:

1. A. E. Arbuzov Institute of Organic and Physical Chemistry

2. Russian Academy of Sciences

3. 420088 Kazan

4. Russia

5. Kazan (Volga Region) Federal University

6. E. K. Zavoisky Kazan Physical-Technical Institute

7. Kazan

Abstract

New rearrangement of P–C-isomer to P–O-isomer in cage phosphoranes series with a high stereoselectivity (>96%) is revealed.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA17983E

Reference51 articles.

1. Phosphoryl group transfer: evolution of a catalytic scaffold

2. Chemical Confirmation of a Pentavalent Phosphorane in Complex with β-Phosphoglucomutase

3. Biological Phosphoryl-Transfer Reactions: Understanding Mechanism and Catalysis

4. Atomic details of near-transition state conformers for enzyme phosphoryl transfer revealed by Formula rather than by phosphoranes

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