Group 12 metal complexes of (2-piperazine-1-yl-ethyl)-pyridin-2-yl-methylene-amine: rare participation of terminal piperazine N in coordination leads to structural diversity

Author:

Purkait Suranjana1234,Aullón Gabriel5678,Zangrando Ennio9101112,Chakraborty Prateeti11314154ORCID

Affiliation:

1. Department of Chemistry

2. University of Calcutta

3. Kolkata-700 009

4. India

5. Departament de Química Inorganica and Institut de Química Teorica i Computacional

6. Universitat de Barcelona

7. 08028 Barcelona

8. Spain

9. Department of Chemical and Pharmaceutical Sciences

10. University of Trieste

11. 34127 Trieste

12. Italy

13. School of Basic Sciences and Research

14. Sharda University

15. Greater Noida

Abstract

Changing from 3d10–4d10–5d10 in presence of a Schiff-base ligand we obtained complexes having different nuclearities with participation of piperazine nitrogen. DFT analysis confirms coordination environment around metal centre.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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