Iminoxyl radicalsvs. tert-butylperoxyl radical in competitive oxidative C–O coupling with β-dicarbonyl compounds. Oxime ether formation prevails over Kharasch peroxidation-Reference-Cited by-同舟云学术

Iminoxyl radicalsvs. tert-butylperoxyl radical in competitive oxidative C–O coupling with β-dicarbonyl compounds. Oxime ether formation prevails over Kharasch peroxidation

Published:2018 Issue:11 Volume:8 Page:5670-5677
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Krylov I. B.¹²³,Paveliev S. A.¹²³,Shumakova N. S.¹²³,Syroeshkin M. A.¹²³,Shelimov B. N.¹²³,Nikishin G. I.¹²³,Terent'ev A. O.¹²³^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

2. Moscow 119991

3. Russian Federation

Abstract

The Kharasch peroxidation system Cu(ii)_cat./t-BuOOH, the source oft-BuOO˙ radicals, can be switched to generate iminoxyl radicals by adding various oximes.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA13587D

Reference74 articles.

1. Recent Advances in C–H Functionalization

2. Recent Advances in Radical C–H Activation/Radical Cross-Coupling

3. Function-Oriented Synthesis, Step Economy, and Drug Design