Regioselective formylation of rhenium-oxo and gold corroles: substituent effects on optical spectra and redox potentials-Reference-Cited by-同舟云学术

Regioselective formylation of rhenium-oxo and gold corroles: substituent effects on optical spectra and redox potentials

Published:2021 Issue:54 Volume:11 Page:34086-34094
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Einrem Rune F.¹,Jonsson Einar Torfi¹,Teat Simon J.²^ORCID,Settineri Nicholas S.²³^ORCID,Alemayehu Abraham B.¹,Ghosh Abhik¹^ORCID

Affiliation:

1. Department of Chemistry, UiT – The Arctic University of Norway, N-9037 Tromsø, Norway

2. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720-8229, USA

3. Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, USA

Abstract

Vilsmeier–Haack formylation of ReO and Au meso-triarylcorroles over 16–18 hours affords moderate to good yields (47–65%) of the ReO-3-formyl and Au-3,17-diformyl derivatives in a highly regioselective manner.

Funder

Norges Forskningsråd

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA05525A

Reference51 articles.

1. Electronic Structure of Corrole Derivatives: Insights from Molecular Structures, Spectroscopy, Electrochemistry, and Quantum Chemical Calculations

2. Metal complexes of corrole

3. Electrochemistry of Corroles in Nonaqueous Media

4. The Story of 5d Metallocorroles: From Metal–Ligand Misfits to New Building Blocks for Cancer Phototherapeutics

5. Gold corroles

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