Pd/norbornene-catalyzed sequential ortho-C–H alkylation and ipso-alkynylation: a 1,1-dimethyl-2-alkynol strategy
Author:
Affiliation:
1. Department of Chemistry
2. University of Science and Technology of China
3. Hefei
4. P. R. China
Abstract
A palladium/norbornene-catalyzedortho-C–H alkylation andipso-alkynylation reaction for the synthesis of 2-alkyl-1-alkynyl arenes was reported, where the use of bulky 1,1-dimethyl-2-alkynols led to significant suppression of the formation ofO-alkylation and norbornene alkynylation by-products.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/QO/C5QO00391A
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