Deciphering the grounds of the suitability of acylhydrazones as efficient photoswitches
Author:
Affiliation:
1. Departament de Química
2. Universitat Autònoma de Barcelona
3. 08193 Bellaterra
4. Spain
5. Institut de Biotecnologia i de Biomedicina
Abstract
Calculations on several acylhydrazones are carried out to explain their diverse photochemistry experimentally observed. Results disclose the role of the intramolecular proton transfer or the loss of the azidic proton in the large Stokes shift.
Funder
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03324F
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1. Control of the Structure and Functions of Biomaterials by Light
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1. Trifluoromethylated hydrazones and acylhydrazones as potent nitrogen-containing fluorinated building blocks;Beilstein Journal of Organic Chemistry;2023-11-15
2. Isomerization of bioactive acylhydrazones triggered by light or thiols;Nature Chemistry;2023-06-12
3. On the Computational Design of Azobenzene-Based Multi-State Photoswitches;International Journal of Molecular Sciences;2022-08-04
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