In situ investigation of the mechanochemically promoted Pd–Ce interaction under stoichiometric methane oxidation conditions

Author:

Danielis Maila1ORCID,Divins Núria J.23ORCID,Llorca Jordi23ORCID,Soler Lluís23ORCID,Garcia Xènia23,Serrano Isabel2ORCID,Betancourt Luis E.4,Xu Wenqian5,Rodríguez José A.4ORCID,Senanayake Sanjaya D.4ORCID,Colussi Sara1ORCID,Trovarelli Alessandro1ORCID

Affiliation:

1. Dipartimento Politecnico, Università di Udine, and INSTM, via del Cotonificio 108, 33100 Udine, Italy

2. Institute of Energy Technologies and Department of Chemical Engineering, Universitat Politècnica de Catalunya, EEBE, Eduard Maristany 10-14, 08019 Barcelona, Spain

3. Barcelona Research Center in Multiscale Science and Engineering, Universitat Politècnica de Catalunya, EEBE, Eduard Maristany 10-14, 08019 Barcelona, Spain

4. Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973, USA

5. X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA

Abstract

A stable Pd0/Pd2+ arrangement generated on Pd/CeO2 prepared by mechanochemistry enables high methane activation rates in the absence of excess oxygen being available.

Funder

U.S. Department of Energy

Marie Sklodowska-Curie Actions

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Reference62 articles.

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3. Opportunities and challenges in the development of advanced materials for emission control catalysts

4. Well-to-wheel climate performance of gas and electric vehicles in Europe

5. Exhaust emission factors of greenhouse gases (GHGs) from European road vehicles

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