When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations
Author:
Affiliation:
1. Department of Chemistry
2. The University of Warwick
3. UK
Abstract
A method to determine chain transfer constants in free radical polymerizations that are >1 using molecular weight distribution data.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY00348D
Reference25 articles.
1. THE THERMAL DECOMPOSITION OF METAL ALKYLS IN HYDROGEN—ETHYLENE MIXTURES
2. The Mechanism of Vinyl Polymerizations1
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5. Regulator Theory in Emulsion Polymerization.1 I. Chain Transfer of Low Molecular Weight Mercaptans in Emulsion and Oil-Phase
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