The direct and highly diastereoselective synthesis of 3,4-epoxy-2-piperidones. Application to the total synthesis and absolute configurational assignment of 3α,4α-epoxy-5β-pipermethystine-Reference-Cited by-同舟云学术

The direct and highly diastereoselective synthesis of 3,4-epoxy-2-piperidones. Application to the total synthesis and absolute configurational assignment of 3α,4α-epoxy-5β-pipermethystine

Published:2018 Issue:1 Volume:16 Page:77-88
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Osorio-Nieto Urbano¹²³⁴,Vázquez-Amaya Laura Y.¹²³⁴,Höpfl Herbert⁵⁶⁷⁸⁴^ORCID,Quintero Leticia¹²³⁴,Sartillo-Piscil Fernando¹²³⁴^ORCID

Affiliation:

1. Centro de Investigación de la Facultad de Ciencias Químicas

2. Benemérita Universidad Autónoma de Puebla (BUAP)

3. Puebla

4. México

5. Centro de Investigaciones Químicas

6. Instituto de Investigación en Ciencias Básicas y Aplicadas

7. Universidad Autónoma del Estado de Morelos

8. Cuernavaca

Abstract

The substrate-controlled asymmetric total synthesis and absolute configurational assignment of biologically active 3α,4α-epoxy-5β-pipermethystine is reported.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C7OB02700A

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