Copper and conjugated carbonyls of metal–organic polymers as dual redox centers for Na storage-Reference-Cited by-同舟云学术

Copper and conjugated carbonyls of metal–organic polymers as dual redox centers for Na storage

Published:2024 Issue:6 Volume:15 Page:2133-2140
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Liubin¹^ORCID,Liu Ningbo¹,Zhao Xiaoying¹,Wang Xiaohan¹,Zhang Tong²,Luo Zhiqiang³^ORCID,Li Fujun²^ORCID

Affiliation:

1. College of Chemistry & Materials Science, Key Laboratory of Analytical Science and Technology of Hebei Province, Hebei University, Baoding 071002, China

2. Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China

3. Tianjin Key Lab for Photoelectric Materials & Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

Abstract

A flower-like π–d conjugated MOP (Cu-TABQ) was prepared using tetramino-benzoquinone (TABQ) as an organic ligand and Cu2+ as a transition metal node. It shows dual redox centers of Cu2+/Cu+ and CO/C–O with high reversible capacity for sodium-ion batteries.

Funder

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05023H

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