The saturation of the gas phase acidity of nHF/AlF3 and nHF/GeF4 (n = 1–6) superacids caused by increasing the number of surrounding HF molecules-Reference-Cited by-同舟云学术

The saturation of the gas phase acidity of nHF/AlF3 and nHF/GeF4 (n = 1–6) superacids caused by increasing the number of surrounding HF molecules

Published:2016 Issue:35 Volume:6 Page:29314-29325
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Czapla Marcin¹²³⁴⁵,Anusiewicz Iwona¹²³⁴⁵,Skurski Piotr¹²³⁴⁵

Affiliation:

1. Laboratory of Quantum Chemistry

2. Faculty of Chemistry

3. University of Gdańsk

4. 80-308 Gdańsk

5. Poland

Abstract

The acidic strength of selected Brønsted/Lewis superacids is evaluated on the basis of theoretical calculations carried out at the QCISD/6-311++G(d,p) level.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA02199A

Reference53 articles.

1. Hammett acidity function for some superacid systems. II. Systems sulfuric acid-[fsa], potassium fluorosulfate-[fsa], [fsa]-sulfur trioxide, [fsa]-arsenic pentafluoride, [sfa]-antimony pentafluoride and [fsa]-antimony pentafluoride-sulfur trioxide

2. A STUDY OF SUPERACID SOLUTIONS. I. THE USE OF THE CHLORANIL ELECTRODE IN GLACIAL ACETIC ACID AND THE STRENGTH OF CERTAIN WEAK BASES

3. Stable Carbonium Ions. XXXIX.1 Formation of Alkylcarbonium Ions via Hydride Ion Abstraction from Alkanes in Fluorosulfonic Acid-Antimony Pentafluoride Solution. Isolation of Some Crystalline Alkylcarbonium Ion Salts

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