Water-gas-shift reaction on reduced gold-substituted Ce1−xO2(111) surfaces: the role of Au charge-Reference-Cited by-同舟云学术

Water-gas-shift reaction on reduced gold-substituted Ce1−xO2(111) surfaces: the role of Au charge

Published:2017 Issue:3 Volume:19 Page:2201-2206
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chang Ming-Wen¹²³⁴,Sheu Wen-Shyan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Fu-Jen Catholic University

3. Taiwan

4. Republic of China

Abstract

Au⁺ falls into a relatively favorable condition for catalyzing the WGS reaction due to a compromise between attractive interaction and Coulomb repulsion between the Au and the transferred proton.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C6CP07185F

Reference36 articles.

1. Low-temperature activity of Au/CeO2 for water gas shift reaction, and characterization by ADF-STEM, temperature-programmed reaction, and pulse reaction

2. DFT and In Situ EXAFS Investigation of Gold/Ceria−Zirconia Low-Temperature Water Gas Shift Catalysts: Identification of the Nature of the Active Form of Gold

3. Gold Atoms Stabilized on Various Supports Catalyze the Water–Gas Shift Reaction

4. Gold catalysts for pure hydrogen production in the water–gas shift reaction: activity, structure and reaction mechanism

5. Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts

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