Control parameters for electrochemically relevant materials: the significance of size and complexity

Author:

Maier J.12

Affiliation:

1. Max Planck Institute for Solid State Research

2. 70569 Stuttgart, Germany

Abstract

This contribution is concerned with the control parameters for arriving at defined, electrochemically relevant materials. The treatment is precise as far as the equilibrium situation of simple crystals is concerned, but becomes more and more qualitative if the distance from equilibrium or the (structural or compositional) complexity increases. It proves useful to distinguish between in situ parameters and ex situ parameters, the number ratio of which decreases with increasing distance from equilibrium. A particularly complex situation is met if not only size, shape and phase distribution are important, but even morphological details are of relevance, as it is the case for modern battery electrodes (“electrochemical integrated circuits”). For such cases archetypical examples along with their advantages or disadvantages for electrochemical storage properties are discussed. In this context, special emphasis is placed upon the dimensionality and distribution topology of building elements.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Reference26 articles.

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2. J. Maier , Physical Chemistry of Ionic Materials. Ions and Electrons in Solids , John Wiley & Sons, Ltd , Chichester, West Sussex UK , 2004

3. From Composites to Solid Solutions: Modeling of Ionic Conductivity in the CaF2-BaF2System

4. F. A. Kroeger , Chemistry of Imperfect Crystals , North-Holland , 1964

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