Palladium(0)-catalyzed asymmetric C(sp3)–H arylation using a chiral binol-derived phosphate and an achiral ligand-Reference-Cited by-同舟云学术

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Palladium(0)-catalyzed asymmetric C(sp3)–H arylation using a chiral binol-derived phosphate and an achiral ligand

Published:2017 Issue:2 Volume:8 Page:1344-1349
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Lei¹²³⁴,Melot Romain¹²³⁴,Neuburger Markus¹²³⁴,Baudoin Olivier¹²³⁴^ORCID

Affiliation:

1. University of Basel

2. Department of Chemistry

3. CH-4056 Basel

4. Switzerland

Abstract

High enantioselectivities can be achieved using an appropriate chiral base/achiral ligand combination in Pd⁰-catalyzed C(sp³)–H activation.

Funder

Seventh Framework Programme

Universität Basel

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04006C

Reference70 articles.

1. Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

2. Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

3. Challenge and progress: palladium-catalyzed sp3 C–H activation

4. Recent Advances in Palladium-Catalyzed C(sp3)–H Activation for the Formation of Carbon–Carbon and Carbon–Heteroatom Bonds

5. Evolution of C–H Bond Functionalization from Methane to Methodology

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