Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80-Reference-Cited by-同舟云学术

Reactivity differences of Sc3N@C2n (2n = 68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D5h-C80

Published:2016 Issue:1 Volume:52 Page:64-67
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cerón Maira R.¹²³⁴,Izquierdo Marta¹²³⁴,Alegret Núria⁵⁶⁷⁸,Valdez Juan A.¹²³⁴,Rodríguez-Fortea Antonio⁵⁶⁷⁸,Olmstead Marilyn M.⁹¹⁰¹¹⁴,Balch Alan L.⁹¹⁰¹¹⁴,Poblet Josep M.⁵⁶⁷⁸,Echegoyen Luis¹²³⁴

Affiliation:

1. Deparment of Chemistry

2. University of Texas at El Paso

3. El Paso

4. USA

5. Departament de Química Física i Inorgànica

6. Universitat Rovira i Virgili

7. Tarragona 43007

8. Spain

9. Department of Chemistry

10. University of California at Davis

11. Davis

Abstract

Based on the chemical reactivity differences between Sc₃N@D_5h-C₈₀ and Sc₃N@D₃-C₆₈, Sc₃N@D_5h-C₈₀ was isolated and functionalized, giving rise to five new methano-derivatives.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC07416A

Reference41 articles.

1. Erratum: Small-bandgap endohedral metallofullerenes in high yield and purity

2. A stable non-classical metallofullerene family

3. Bonding within the Endohedral Fullerenes Sc3N@C78 and Sc3N@C80 as Determined by Density Functional Calculations and Reexamination of the Crystal Structure of {Sc3N@C78}·Co(OEP)}·1.5(C6H6)·0.3(CHCl3)

4. An isomer of the endohedral metallofullerene Sc3N@C80 with D5h symmetry

5. Isolation and Characterisation of Two Sc3N@C80 Isomers

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