Breaking conjugation: unusual regioselectivity with 2-substituted allylic substrates in the Tsuji–Trost reaction

Author:

Kim Byeong-Seon1234,Hussain Mahmud M.1234,Norrby Per-Ola56789,Walsh Patrick J.1234

Affiliation:

1. P. Roy and Diana T. Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia, USA

5. University of Gothenburg

6. Department of Chemistry and Molecular Biology

7. SE-412 96 Göteborg, Sweden

8. Pharmaceutical Development

9. Global Medicines Development

Abstract

We describe the unusual regioselectivity of the palladium-catalyzed Tsuji–Trost allylic substitution reaction with 1,2,3-trisubstituted allylic substrates.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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