Effect of temperature on B(C6F5)3-catalysed reduction of germanium alkoxides by hydrosilanes – a new route to germanium nanoparticles
Author:
Affiliation:
1. Centre of Molecular and Macromolecular Studies
2. Polish Academy of Sciences
3. Lodz
4. Poland
Abstract
The reaction of Ge(OBu)4 with PhMe2SiH in the presence of B(C6F5)3 carried out at temperatures above 100 °C provides a simple one-pot method for Ge NPs synthesis under mild conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01555E
Reference43 articles.
1. New Synthetic Strategies for Structured Silicones Using B(C6F5)3
2. New Control Over Silicone Synthesis using SiH Chemistry: The Piers-Rubinsztajn Reaction
3. Siloxane-Bond Formation Promoted by Lewis Acids: A Nonhydrolytic Sol-Gel Process and the Piers-Rubinsztajn Reaction
4. A New Polycondensation Process for the Preparation of Polysiloxane Copolymers
5. Preparation of Polyaryloxysilanes and Polyaryloxysiloxanes by B(C6F5)3 Catalyzed Polyetherification of Dihydrosilanes and Bis-Phenols
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