A novel two-dimensional Janus TiSiGeN4 monolayer with N vacancies for efficient photocatalytic nitrogen reduction

Author:

Sun Zhe12,Guan Rongfeng3,Li Huimin12,Feng Shilong12,Ma Lin12,Shen Qianqian12,Ling Lixia4,Jia Husheng125,Xue Jinbo12ORCID

Affiliation:

1. Key Laboratory of Interface Science and Engineering in Advanced Materials (Taiyuan University of Technology), Ministry of Education, Taiyuan 030024, P. R. China

2. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China

3. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, P. R. China

4. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, P. R. China

5. Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030032, P. R. China

Abstract

A 2D Janus structure facilitates photogenerated carrier separation and transport, and N vacancies promote the adsorption and activation of N2 molecules. These two synergistically achieve efficient photocatalytic nitrogen reduction.

Funder

Shanxi Scholarship Council of China

Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering

Natural Science Foundation of Shanxi Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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