A DFT examination of the role of proximal boron functionalities in the S-alkylation of sulfenic acid anions-Reference-Cited by-同舟云学术

A DFT examination of the role of proximal boron functionalities in the S-alkylation of sulfenic acid anions

Published:2022 Issue:3 Volume:20 Page:649-657
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Durant Andrew G.¹^ORCID,Nicol Eric A.¹^ORCID,McInnes Brandon M.¹,Schwan Adrian L.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Guelph, Guelph, Ontario, Canada N1G 2 W1

Abstract

DFT modelling predicts proximal boron groups can accelerate sulfenate alkylation reactions, depending on boron substituents and boron distance from the reaction site.

Funder

University of Guelph

Compute Canada

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB02083H

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