Phosphorus–nitrogen compounds. Part 64. Comparative reactions of spiro and ansa (N/O) cyclotetraphosphazenes with bulky (4-fluorobenzyl) N/N and N/O donor type bidentate reagents: structure, stereogenic properties and cytotoxic activity studies

Author:

Elmas Gamze1ORCID,Binici Arzu2,Yakut Mehtap1ORCID,Okumuş Aytuğ1ORCID,Kılıç Zeynel1ORCID,Çoşut Bünyemin3,Hökelek Tuncer4,Çerçi Nebahat Aytuna5ORCID,Açık Leyla6

Affiliation:

1. Department of Chemistry, Ankara University, 06100 Ankara, Turkey

2. Republic Health Institution of Türkiye, 06100 Ankara, Turkey

3. Department of Chemistry, Gebze Technical University, 41400 Gebze-Kocaeli, Turkey

4. Department of Physics, Hacettepe University, 06800 Ankara, Turkey

5. Department of Bioengineering, Kırıkkale University, 71450 Yahşihan-Kırıkkale, Turkey

6. Department of Biology, Gazi University, 06500 Ankara, Turkey

Abstract

Novel inorganic–organic hybrid multiheterocyclic-spiro and ansa cyclotetraphosphazenes were synthesized. The spectral, crystallographic, and stereogenic properties, and the cytotoxic activities of the compounds were presented.

Funder

Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

Türkiye Bilimler Akademisi

Hacettepe Üniversitesi

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference71 articles.

1. V.Chandrasekhar and A.Chakraborty , Organophosphorus Chem. , Royal Society of Chemistry (RSC Publishing) , 2021 , vol. 50, pp. 429–466

2. V.Chandrasekhar , Inorganic and Organometallic Polymers , Springer-Verlag Berlin and Heidelberg GmbH & Co. KG , Germany , 2005

3. M.Gleria and R. D.Jaeger , A Worldwide Insight , Nova Science Publishers , New York , 2004 , p. 1047

4. V.Chandrasekhar and R. S.Narayanan , Organophosphorus Chem. , Royal Society of Chemistry (RSC Publishing) , 2016 , vol. 45, pp. 375–437

5. Phosphorus–nitrogen compounds: part 16. Synthesis, stereogenism, anisochronism and the relationship between 31P NMR spectral and crystallographic data of monotopic spiro-crypta phosphazene derivatives

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