Double exchange in a mixed-valent octanuclear iron cluster, [Fe8(μ4-O)4(μ-4-Cl-pz)12Cl4]−

Author:

Zueva Ekaterina M.12345,Herchel Radovan65789,Borshch Serguei A.10111213,Govor Evgen V.141516,Sameera W. M. C.1234,McDonald Ross171819,Singleton John171819,Krzystek Jurek1720,Trávníček Zdeněk65789,Sanakis Yiannis212223,McGrady John E.1234,Raptis Raphael G.141516

Affiliation:

1. Department of Chemistry

2. Inorganic Chemistry Laboratory

3. University of Oxford

4. Oxford, UK

5. Department of Inorganic Chemistry

6. Regional Centre of Advanced Technologies and Materials

7. Faculty of Science

8. Palacký University

9. CZ-771 46 Olomouc, Czech Republic

10. Laboratoire de Chimie

11. UMR 5182

12. Ecole Normale Supérieure de Lyon

13. 69364 Lyon Cedex 07, France

14. Department of Chemistry and the Institute for Functional Nanomaterials

15. University of Puerto Rico

16. San Juan, USA

17. National High Magnetic Field Laboratory

18. Los Alamos National Laboratories

19. Los Alamos, USA

20. Tallahassee, USA

21. Institute of Materials Science

22. NCRS “Demokritos”

23. Athens, Greece

Abstract

The influence of double exchange on the magnetic properties of a mixed-valent Fe4O8 cluster is highly dependent on temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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