Polariton-assisted manipulation of energy relaxation pathways: donor–acceptor role reversal in a tuneable microcavity

Author:

Dovzhenko Dmitriy12ORCID,Lednev Maksim1,Mochalov Konstantin13,Vaskan Ivan134,Rakovich Yury56,Karaulov Alexander7ORCID,Nabiev Igor178ORCID

Affiliation:

1. National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 115409 Moscow, Russia

2. Department of Physics and Astronomy, University of Southampton, Southampton, SO17 1BJ, UK

3. Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997 Moscow, Russia

4. Moscow Institute of Physics and Technology, Dolgoprudny, 141701 Moscow, Russia

5. IKERBASQUE, Basque Foundation for Science, 48009 Bilbao, Spain

6. Donostia International Physics Center, Polímeros y Materiales Avanzados: Física, Química y Tecnología, UPV-EHU, Centro de Física de Materiales (MPC, CSIC-UPV/EHU), 20018 Donostia – San Sebastian, Spain

7. Sechenov First Moscow State Medical University (Sechenov University), 119146 Moscow, Russia

8. Laboratoire de Recherche en Nanosciences, LRN-EA4682, Université de Reims Champagne-Ardenne, 51100 Reims, France

Abstract

Polariton-assisted donor–acceptor role reversal in resonant energy transfer between organic dyes tagged with the terminus of the closed oligonucleotide-based molecular beacon strongly coupled to electromagnetic modes of a tuneable microcavity.

Funder

Ministry of Education and Science of the Russian Federation

Université de Reims Champagne-Ardenne

Russian Science Foundation

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Eusko Jaurlaritza

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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