Gradient helical copolymers: synthesis, chiroptical properties, thermotropic liquid crystallinity, and self-assembly in selective organic solvents
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Science
2. Key Laboratory of Polymer Chemistry and Physics of Ministry of Education
3. College of Chemistry and Molecular Engineering
4. Peking University
5. Beijing 100871
Abstract
A series of novel gradient copolymers R-(−)-poly(StN-grad-C8) were synthesized through atom transfer radical copolymerization of an achiral styrenic monomer, N,N-dimethyl-4-ethenylbenzamide (M-StN), and a chiral bulky vinylterphenyl monomer, (−)-2,5-bis{4′-[(R)-sec-octyloxycarbonyl]phenyl}styrene (R-(−)-M-C8).
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY00237A
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