Modulation of charge transfer exciton dynamics in organic semiconductors using different structural arrangements

Author:

Soncini Cristian1ORCID,Kumar Abhishek2,Bondino Federica1ORCID,Magnano Elena13ORCID,Stupar Matija4,Ressel Barbara4,De Ninno Giovanni45,Papadopoulos Antonis6,Serpetzoglou Efthymis6ORCID,Stratakis Emmanuel6ORCID,Pedio Maddalena1ORCID

Affiliation:

1. Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche, Trieste, Italy

2. Department of Physics, Chandigarh University, Chandigarh, India

3. Department of Physics, University of Johannesburg, Johannesburg, South Africa

4. Laboratory of Quantum Optics, University of Nova Gorica, Ajdovščina, Slovenia

5. Elettra – Sincrotrone Trieste S.C.p.A, Trieste, Italy

6. FORTH Institute of Electronic Structure and Laser Foundation for Research and Technology Hellas and University Of Crete, Hellas, Heraklion, Crete, Greece

Abstract

A dependence of the CT exciton lifetime on the cobalt phthalocyanine molecular stacking is observed. We ascribe such behavior to the different π-conjugation along the stacking axis, favoring the CT exciton delocalization in the herringbone geometry.

Funder

Elettra-Sincrotrone Trieste

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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