Floating zone crystal growth, structure, and properties of a cubic Li5.5La3Nb1.5Zr0.5O12 garnet-type lithium-ion conductor

Author:

Ramette Caleb1ORCID,Pressley Lucas23,Avdeev Maxim45ORCID,Lee Minseong6,Kushwaha Satya27,Krogstad Matthew8,Sarker Suchismita9,Cardon Paul1,Ruff Jacob9,Khan Mojammel27,Kataoka Kunimitsu10ORCID,McQueen Tyrel237ORCID,Ji Huiwen1

Affiliation:

1. Department of Materials Science & Engineering, University of Utah, Salt Lake City, Utah 84112, USA

2. Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland, 21218, USA

3. Department of Materials Science and Engineering, The Johns Hopkins University, Baltimore, Maryland, 21218, USA

4. Australian Centre for Neutron Scattering, Australian Nuclear Science and Technology Organisation (ANSTO), New Illawarra Rd, Lucas Heights, Sydney, NSW 2234, Australia

5. School of Chemistry, University of Sydney, Sydney, NSW, 2006, Australia

6. National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

7. Department of Chemistry, Platform for the Accelerated Realization, Analysis and Discovery of Interface Materials (PARADIM), The Johns Hopkins University, Baltimore, Maryland, 21218, USA

8. Advanced Photon Source, Argonne National Laboratory, Lemont, IL, 60439, USA

9. Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY, 14853, United States

10. National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Centre 5, Japan

Abstract

Floating zone growth of a cm-sized solid-state electrolyte single crystal, identification of two distinct Li sites with Laue neutron diffraction, and Li-ion conductivity and migration energy determination by EIS and dielectric measurements.

Funder

National Science Foundation

University of Utah

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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