Selective suppression of {112} anatase facets by fluorination for enhanced TiO2 particle size and phase stability at elevated temperatures

Author:

Kohlrausch Emerson C.12,dos Reis Roberto3ORCID,Lodge Rhys W.2ORCID,Vicente Isabel4,Brolo Alexandre G.5ORCID,Dupont Jairton1ORCID,Alves Fernandes Jesum2ORCID,Santos Marcos. J. L.1ORCID

Affiliation:

1. Instituto de Química – UFRGS, 91501-970, Porto Alegre, RS, Brazil

2. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK

3. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, USA

4. Unitat de Tecnologíe Químiques, EURECAT, Tarragona, 43007 Spain

5. Department of Chemistry, University of Victoria, P. O. Box 3065, V8W 3V6, BC, Canada

Abstract

Fluorinated ionic liquids are used to finely control the exposure of {112} facets on the TiO2 surface enabling an exquisite temperature control of the anatase-to-rutile phase transition.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Engineering and Physical Sciences Research Council

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

University of Nottingham

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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