The influence of the sample dispersion on a solid surface in the thermal spin transition of [Fe(pz)Pt(CN)4] nanoparticles

Author:

Delgado Teresa1234,Enachescu Cristian5678,Tissot Antoine910111213,Guénée Laure14234,Hauser Andreas1234,Besnard Céline14234ORCID

Affiliation:

1. Départment de Chimie Physique

2. Université de Genève

3. CH-1211 Genève

4. Switzerland

5. Faculty of Physics

6. “Alexandru Ioan Cuza” University

7. Iasi

8. Romania

9. Institut des Matériaux Poreux de Paris

10. FRE 2000 CNRS

11. Ecole Normale Supérieure

12. Ecole Supérieure de Physique et de Chimie Industrielle de Paris

13. PSL Research University

14. Laboratoire de Cristallographie

Abstract

The dispersion on a Sapphire surface of [Fe(pz)Pt(CN)4], pz = pyrazine nanoparticles influences the thermal spin transition, as shown using magnetic, spectroscopic and diffraction data. This is explained within the framework of the mechanoelastic model.

Funder

Consiliul National al Cercetarii Stiintifice

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference49 articles.

1. Spin-crossover materials: properties and applications , ed. M. A. Halcrow , John Wiley & Sons Ltd. , 2013

2. Pressure effect studies on spin crossover systems

3. Thermal and Optical Switching of Iron(II) Complexes

4. Light-Induced Spin Crossover and the High-Spin→Low-Spin Relaxation

5. Y. Garcia , V.Niel , M. C.Muñoz and J. A.Real , in Spin Crossover in Transition Metal Compounds I , ed. P. Gütlich and H. A. Goodwin , Springer Berlin Heidelberg , Berlin, Heidelberg , 2004 , pp. 229–257

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